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银/氧化锌-C纳米复合材料的制备及其光催化性能

Ag/ZnO-C nanocomposite-preparation and photocatalytic properties.

作者信息

Yin Dongguang, Le Zhang, Liu Binhu, Wu Minghong

机构信息

College of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China.

出版信息

J Nanosci Nanotechnol. 2012 Mar;12(3):2248-53. doi: 10.1166/jnn.2012.5762.

Abstract

In this present study, Ag-hybridized ZnO was prepared through a powder-sol method first, then Ag/ZnO-AC (activated carbon) composite was synthesized by a adsorption method using Ag/ZnO and AC as precursors. The structure and morphology of as-prepared samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectrum (FT-IR), Raman spectra, and diffuse reflectance absorption spectra, respectively. The photocatalytic performances of the prepared catalysts were investigated by photocatalystic degradation of methyl orange. The influences of initial pH value, initial dye concentration and the calcination temperature on the photocatalytic activity of the catalysts were investigated and the results were discussed. Comparing with pure ZnO and ZnO-AC, Ag/ZnO-AC composite showed greatly enhanced photocatalytic activity. The results demonstrate that the hybridization of silver, activated carbon and ZnO can significantly improve the photocatalytic activity of ZnO. This work could provide new insights into the fabrication of noble metal/ZnO-carbon based composites and facilitate their application in environmental protection issues.

摘要

在本研究中,首先通过粉末溶胶法制备了银掺杂的氧化锌,然后以银/氧化锌和活性炭为前驱体,采用吸附法合成了银/氧化锌-活性炭(AC)复合材料。分别利用X射线衍射(XRD)、扫描电子显微镜(SEM)、傅里叶变换红外光谱(FT-IR)、拉曼光谱和漫反射吸收光谱对所制备样品的结构和形貌进行了表征。通过光催化降解甲基橙研究了所制备催化剂的光催化性能。研究了初始pH值、初始染料浓度和煅烧温度对催化剂光催化活性的影响,并对结果进行了讨论。与纯氧化锌和氧化锌-活性炭相比,银/氧化锌-活性炭复合材料表现出大大增强的光催化活性。结果表明,银、活性炭与氧化锌的杂化能够显著提高氧化锌的光催化活性。这项工作可为贵金属/氧化锌-碳基复合材料的制备提供新的见解,并促进其在环境保护问题中的应用。

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