Department of General and Inorganic Chemistry, Faculty of Chemistry, Aristotle University of Thessaloniki, GR-54124 Thessaloniki, Greece.
Inorg Chem. 2012 Jul 16;51(14):7460-2. doi: 10.1021/ic3010757. Epub 2012 Jul 3.
The interaction of ZnCl(2) with 2-dipyridylketonoxime (=Hpko) and flufenamic acid (=Hfluf) in a basic methanolic solution leads to the formation of a hexanuclear 24-membered metallacoronate, [Zn(6)(OH)(2)(pko)(4)(fluf)(6)] (1), with a [Zn-O-C-O] repeat unit and a nonsteroidal antiinflammatory drug as the constructing ligand. Compound 1 retains its structure in a dimethyl sulfoxide solution, as shown by (1)H NMR spectroscopy and molar conductance.
在碱性甲醇溶液中，ZnCl(2)与 2-二吡啶酮肟（=Hpko）和氟芬那酸（=Hfluf）相互作用，生成了一种具有[Zn-O-C-O]重复单元的六核 24 元金属碳酸盐，[Zn(6)(OH)(2)(pko)(4)(fluf)(6)]（1），其中非甾体抗炎药物作为构筑配体。通过（1）H NMR 光谱和摩尔电导率表明，化合物 1 在二甲亚砜溶液中保留其结构。
