在碳酸盐存在下，高效微波辅助 Pd 催化的芳基氯化物的羟化反应。
Efficient microwave-assisted Pd-catalyzed hydroxylation of aryl chlorides in the presence of carbonate.
机构信息
School of Pharmacy, College of Medicine, National Taiwan University , Taipei, 10051, Taiwan, Republic of China, Department of Applied Chemistry, Providence University , Taichung 43301, Taiwan, Republic of China, and Department of Life Science, College of Life Science, National Taiwan University , Taipei 10617, Taiwan, Republic of China.
出版信息
Org Lett. 2012 Jul 20;14(14):3688-91. doi: 10.1021/ol301523q. Epub 2012 Jul 3.
An efficient microwave-assisted, palladium-catalyzed hydroxylation of aryl chlorides in the presence of a weak base carbonate was developed, which rapidly converts aryl and heteroaryl chlorides to phenols, and can be used when the aryl chloride is functionalized with a ketone, aldehyde, ester, nitrile, or amide.
开发了一种在弱碱碳酸酯存在下，利用高效微波辅助钯催化的芳基氯化物羟化方法，该方法可以快速将芳基和杂芳基氯化物转化为酚，并且可以在芳基氯化物带有酮、醛、酯、腈或酰胺等官能团时使用。
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