由D-葡萄糖酸-1,5-内酯合成一些单脱氧和双脱氧己糖醇及其衍生物。
Synthesis of some monodeoxy- and dideoxy-hexitols, and derivatives thereof, from D-glucono-1,5-lactone.
作者信息
Regeling H, Chittenden G J
机构信息
Department of Organic Chemistry, University, Toernooiveld, Nijmegen, The Netherlands.
出版信息
Carbohydr Res. 1990 Sep 19;205:261-8. doi: 10.1016/0008-6215(90)80145-s.
PMID:2276138
Abstract
Syntheses of 2-deoxy-D-arabino-hexitol (1), D-rhamnitol (2), 1,2-dideoxy-D-arabino-hexitol (3), 2,3-dideoxy-D-erythro-hexitol (4), and some derivatives thereof are described. These compounds were obtained by reductive sequences on various compounds formed from methyl 3,4:5,6-di-O-isopropylidene-D-gluconate (9).
摘要
描述了2-脱氧-D-阿拉伯己糖醇（1）、D-鼠李糖醇（2）、1,2-二脱氧-D-阿拉伯己糖醇（3）、2,3-二脱氧-D-赤藓己糖醇（4）及其一些衍生物的合成。这些化合物是通过对由3,4:5,6-二-O-异亚丙基-D-葡萄糖酸甲酯（9）形成的各种化合物进行还原序列反应得到的。
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