School of Chemical and Physical Sciences, Victoria University of Wellington, PO Box 600, Wellington, New Zealand.
Chem Commun (Camb). 2012 Aug 18;48(64):7961-3. doi: 10.1039/c2cc31465g. Epub 2012 Jul 5.
Controlled aggregation of perylene bisimides in multiple modes has been achieved via symmetric substitution with peptides. Using optical probes of aggregation, the balance of hydrophobic and electrostatic forces are found to play a key role in directing self assembly and are exploited via solvent, pH, and specific extrinsic ion effects.
通过与肽的对称取代，实现了苝二酰亚胺的多种模式的可控聚集。利用聚集的光学探针，发现疏水力和静电力的平衡在指导自组装中起着关键作用，并通过溶剂、pH 值和特定的外源性离子效应加以利用。
