Centre for Organized Matter Chemistry, School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK.
Chem Commun (Camb). 2012 Aug 18;48(64):7934-6. doi: 10.1039/c2cc33351a. Epub 2012 Jul 5.
Hybrid supramolecular hydrogels are prepared by non-enzymatic dephosphorylation of N-fluorenylmethyloxycarbonyl tyrosine-(O)-phosphate (FMOC-Tyr-P) using catalytic cerium oxide nanoparticles. The organic-inorganic hydrogels exhibit enhanced viscoelastic properties compared with analogous materials prepared using alkaline phosphatase.
采用铈氧化物纳米粒子作为催化剂，通过非酶促法对 N-芴甲氧羰基酪氨酸-O-磷酸酯（FMOC-Tyr-P）进行去磷酸化反应，制备了杂化超分子水凝胶。与使用碱性磷酸酶制备的类似材料相比，该有机-无机水凝胶表现出增强的粘弹性。
