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用于高比能吸收的周期性双连续复合材料。

Periodic bicontinuous composites for high specific energy absorption.

机构信息

Department of Materials Science and Engineering, Massuchusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.

出版信息

Nano Lett. 2012 Aug 8;12(8):4392-6. doi: 10.1021/nl302234f. Epub 2012 Jul 13.

Abstract

We report on the mechanical behavior of an interpenetrating carbon/epoxy periodic submicrometer-scale bicontinuous composite material fabricated following the design principles deduced from biological composites. Using microscopic uniaxial compressive tests, the specific energy absorption is quantitatively evaluated and compared with the epoxy/air and carbon/air precursors. The carbon/epoxy material demonstrates extremely high specific energy absorption up to 720 kJ/kg and shear-dominant interphase interactions from the interlocked hard (carbon) and soft (epoxy) phases. Such bicontinuous nanocomposites are a new type of structural metamaterial with designed cell topology and mechanical anisotropy. Their inherent small length scale can play a critical role in prohibiting segregated mechanical responses leading to flaw tolerance.

摘要

我们报告了一种贯穿式碳/环氧亚微米级双连续复合材料的力学行为,该材料是根据从生物复合材料中推导出来的设计原则制造的。通过微观单轴压缩试验,定量评估了比能量吸收并与环氧/空气和碳/空气前体进行了比较。碳/环氧材料表现出极高的比能量吸收,高达 720 kJ/kg,并且具有由互锁硬(碳)和软(环氧)相产生的剪切主导的界面相互作用。这种双连续纳米复合材料是一种具有设计的单元拓扑和机械各向异性的新型结构超材料。其固有的小尺寸在阻止导致缺陷容忍的分离力学响应方面可以发挥关键作用。

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