Shi-Changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, 110016, Shenyang, China.
School of Materials Science and Engineering, University of Science and Technology of China, 230026, Hefei, China.
Nat Commun. 2022 Jun 6;13(1):3247. doi: 10.1038/s41467-022-30873-9.
Bioinspired architectures are effective in enhancing the mechanical properties of materials, yet are difficult to construct in metallic systems. The structure-property relationships of bioinspired metallic composites also remain unclear. Here, Mg-Ti composites were fabricated by pressureless infiltrating pure Mg melt into three-dimensional (3-D) printed Ti-6Al-4V scaffolds. The result was composite materials where the constituents are continuous, mutually interpenetrated in 3-D space and exhibit specific spatial arrangements with bioinspired brick-and-mortar, Bouligand, and crossed-lamellar architectures. These architectures promote effective stress transfer, delocalize damage and arrest cracking, thereby bestowing improved strength and ductility than composites with discrete reinforcements. Additionally, they activate a series of extrinsic toughening mechanisms, including crack deflection/twist and uncracked-ligament bridging, which enable crack-tip shielding from the applied stress and lead to "Γ"-shaped rising fracture resistance R-curves. Quantitative relationships were established for the stiffness and strengths of the composites by adapting classical laminate theory to incorporate their architectural characteristics.
受生物启发的结构在增强材料的机械性能方面非常有效,但在金属系统中很难构建。受生物启发的金属复合材料的结构-性能关系也不清楚。在这里,通过无压将纯 Mg 熔体渗透到 3D 打印的 Ti-6Al-4V 支架中,制备了 Mg-Ti 复合材料。结果是复合材料的成分是连续的,在 3D 空间中相互渗透,并具有特定的空间排列,具有生物启发的砖-灰泥、Bouligand 和交错层状结构。这些结构促进了有效应力传递、损伤弥散和裂纹止裂,从而赋予了比具有离散增强体的复合材料更好的强度和延展性。此外,它们还激活了一系列外部分化增韧机制,包括裂纹偏转/扭转和未开裂韧带桥接,从而使裂纹尖端免受施加的应力,并导致“Γ”形上升的断裂阻力 R 曲线。通过将经典层合板理论适应于包含其建筑特征,为复合材料的刚度和强度建立了定量关系。