College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Tianjin Normal University, Tianjin, 300387, P.R. China.
Dalton Trans. 2012 Aug 28;41(32):9611-4. doi: 10.1039/c2dt30496a. Epub 2012 Jul 13.
A (3, 4, 14)-connected framework with complicated distorted triangular magnetic lattices, {[Co(7)(H(2)O)(4)(trz)(8)(sip)(2)]·3H(2)O}(n) (trz = 1,2,4-triazolate, sip = 5-sulfoisophthalate), exhibits continuous field-induced metamagnetic transition from an antiferromagnetic ordering to a ferrimagnetic state at 15 kOe, spin competition at 26 kOe and spin reorientation at 50 kOe, respectively.
一个具有复杂扭曲三角形磁晶格的(3, 4, 14)-连接骨架,{[Co(7)(H(2)O)(4)(trz)(8)(sip)(2)]·3H(2)O}(n) (trz = 1,2,4-三唑,sip = 5-磺基间苯二甲酸),在 15 kOe 时表现出连续的场诱导顺磁转变,从反铁磁有序到铁磁态,在 26 kOe 时表现出自旋竞争,在 50 kOe 时表现出自旋重取向。