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一种(3, 4, 14)连接的骨架,具有各种扭曲的三角磁晶格,表现出场致顺磁体、自旋竞争和自旋重定向。

A (3, 4, 14)-connected framework with various distorted triangular magnetic lattices exhibiting field-induced metamagnetism, spin competition and spin reorientation.

机构信息

College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Tianjin Normal University, Tianjin, 300387, P.R. China.

出版信息

Dalton Trans. 2012 Aug 28;41(32):9611-4. doi: 10.1039/c2dt30496a. Epub 2012 Jul 13.

DOI:10.1039/c2dt30496a
PMID:22790974
Abstract

A (3, 4, 14)-connected framework with complicated distorted triangular magnetic lattices, {[Co(7)(H(2)O)(4)(trz)(8)(sip)(2)]·3H(2)O}(n) (trz = 1,2,4-triazolate, sip = 5-sulfoisophthalate), exhibits continuous field-induced metamagnetic transition from an antiferromagnetic ordering to a ferrimagnetic state at 15 kOe, spin competition at 26 kOe and spin reorientation at 50 kOe, respectively.

摘要

一个具有复杂扭曲三角形磁晶格的(3, 4, 14)-连接骨架,{[Co(7)(H(2)O)(4)(trz)(8)(sip)(2)]·3H(2)O}(n) (trz = 1,2,4-三唑,sip = 5-磺基间苯二甲酸),在 15 kOe 时表现出连续的场诱导顺磁转变,从反铁磁有序到铁磁态,在 26 kOe 时表现出自旋竞争,在 50 kOe 时表现出自旋重取向。

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