Gowda B Thimme, Foro Sabine, Kumar Sharatha
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2128. doi: 10.1107/S1600536812026244. Epub 2012 Jun 16.
The asymmetric unit of the title compound, C(10)H(12)N(2)OS, contains two independent mol-ecules. In both mol-ecules, the conformations of the two N-H bonds are anti to each other. Furthermore, the conformations of the amide C=S bonds and the C=O bonds are anti to each other. The dihedral angles between the benzene ring and the side chain are 52.8 (1) and 68.0 (1)° in the two independent mol-ecules. An intra-molecular N-H⋯O hydrogen bond occurs in both independent mol-ecules. In the crystal, mol-ecules are linked into infinite chains along the a axis through a series of N-H⋯O and N-H⋯S hydrogen bonds.
标题化合物C(10)H(12)N(2)OS的不对称单元包含两个独立的分子。在这两个分子中，两个N-H键的构象彼此相反。此外，酰胺C=S键和C=O键的构象也彼此相反。在两个独立分子中，苯环与侧链之间的二面角分别为52.8 (1)°和68.0 (1)°。在两个独立分子中均存在分子内N-H⋯O氢键。在晶体中，分子通过一系列N-H⋯O和N-H⋯S氢键沿a轴连接成无限链。
