2-肼基喹啉
2-Hydrazinyl-quinoline.
作者信息
Najib Muhd Hidayat Bin, Tan Ai Ling, Young David J, Ng Seik Weng, Tiekink Edward R T
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2138. doi: 10.1107/S1600536812026906. Epub 2012 Jun 20.
Abstract
In the title compound, C(9)H(9)N(3), the 12 non-H atoms are essentially planar (r.m.s. deviation = 0.068 Å). The maximum deviation from planarity is reflected in the torsion angle between the β-N atom of the hydrazinyl residue and the quinolinyl N atom [N-N-C-N = -12.7 (3)°]; these atoms are syn. In the crystal, supra-molecular layers in the bc plane are formed via N-H⋯N hydrogen bonds.
摘要
在标题化合物C₉H₉N₃中，12个非氢原子基本处于同一平面（均方根偏差 = 0.068 Å）。平面度的最大偏差体现在肼基残基的β-N原子与喹啉基N原子之间的扭转角上[N-N-C-N = -12.7 (3)°]；这些原子呈顺式。在晶体中，通过N-H⋯N氢键在bc平面形成超分子层。
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