来自同步辐射的(2E)-N'-[(E)-亚苄基]-3-苯基-2-烯酰肼
(2E)-N'-[(E)-Benzyl-idene]-3-phenyl-prop-2-enohydrazide from synchrotron radiation.
作者信息
Carvalho Samir A, da Silva Edson F, Fraga Carlos A M, Wardell Solange M S V, Wardell James L, Tiekink Edward R T
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2255-6. doi: 10.1107/S1600536812028504. Epub 2012 Jun 30.
In the title compound, C(16)H(14)N(2)O, the dihedral angle between the phenyl rings is 25.48 (12)°. An E conformation is found for each of the imine [1.269 (3) Å] and ethyl-ene [1.313 (3) Å] bonds. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds, leading to zigzag chains along [010]. Supra-molecular layers in the ab plane are formed, whereby the chains are linked by C-H⋯N and C-H⋯π inter-actions.
在标题化合物C(16)H(14)N(2)O中，苯环之间的二面角为25.48 (12)°。亚胺键[1.269 (3) Å]和乙烯键[1.313 (3) Å]均呈E构象。在晶体中，分子通过N-H⋯O氢键相连，形成沿[010]方向的锯齿链。在ab平面上形成超分子层，链通过C-H⋯N和C-H⋯π相互作用相连。
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