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1-氯-1-[(Z)-2-苯基肼-1-基亚基]丙酮

1-Chloro-1-[(Z)-2-phenyl-hydrazin-1-yl-idene]propan-2-one.

作者信息

Abdel-Aziz Hatem A, Chia Tze Shyang, Fun Hoong-Kun

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2263. doi: 10.1107/S1600536812028759. Epub 2012 Jun 30.

DOI:10.1107/S1600536812028759
PMID:22798911
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3394046/
Abstract

The title compound, C(9)H(9)ClN(2)O, is close to planar (r.m.s. deviation for the non-H atoms = 0.0446 Å); it exists in a cis conformation with respect to the C=N double bond. In the crystal, the ketone O atom accepts both N-H⋯O and C-H⋯O hydrogen bonds, which leads to [010] infinite chains incorporating R(2) (1)(6) loops. The crystal structure also features a C-H⋯π inter-action.

摘要

标题化合物C(9)H(9)ClN(2)O接近平面结构（非氢原子的均方根偏差 = 0.0446 Å）；相对于C=N双键，它以顺式构象存在。在晶体中，酮O原子接受N-H⋯O和C-H⋯O氢键，这导致形成包含R(2) (1)(6)环的[010]无限链。晶体结构还具有C-H⋯π相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2053/3394046/3dd4016749eb/e-68-o2263-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2053/3394046/add85b729ce8/e-68-o2263-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2053/3394046/3dd4016749eb/e-68-o2263-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2053/3394046/add85b729ce8/e-68-o2263-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2053/3394046/3dd4016749eb/e-68-o2263-fig2.jpg

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