1,6 - 双[(2,2':6',2'' - 三联吡啶 - 4' - 基) - 氧基]己烷
1,6-Bis[(2,2':6',2''-terpyridin-4'-yl)-oxy]hexa-ne.
作者信息
Nikolayenko Varvara I, Akerman Matthew P, Grimmer Craig D, Reddy Desigan
机构信息
University of KwaZulu-Natal, School of Chemistry and Physics, Private Bag X01, Scottsville 3209, Pietermaritzburg, South Africa.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2272-3. doi: 10.1107/S1600536812029017. Epub 2012 Jun 30.
Abstract
The mol-ecule of the title compound, C(36)H(32)N(6)O(2), lies about an inversion center, located at the mid-point of the central C-C bond of the diether bridge. The terminal pyridine rings form dihedral angles of 4.67 (7) and 26.23 (7)° with the central ring. In the crystal, weak C-H⋯N and C-H⋯O inter-actions link the mol-ecules into a three-dimensional network.
摘要
标题化合物C(36)H(32)N(6)O(2)的分子位于一个对称中心上，该对称中心位于二醚桥中心C-C键的中点。末端吡啶环与中心环形成的二面角分别为4.67 (7)°和26.23 (7)°。在晶体中，弱的C-H⋯N和C-H⋯O相互作用将分子连接成三维网络。
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