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2-[(E)-({3-[(E)-(2-羟基苯亚甲基)氨基甲基]-1,4-二氧杂螺[4.5]癸烷-2-基}甲基)亚氨基甲基]苯酚

2-[(E)-({3-[(E)-(2-Hy-droxy-benzyl-idene)amino-meth-yl]-1,4-dioxaspiro-[4.5]decan-2-yl}meth-yl)imino-meth-yl]phenol.

作者信息

Jiang Yan, Wang Lili, Bian Jing, Du Xiaoying, Sun Xiaoqiang

机构信息

Key Laboratory of Fine Chemical Engineering, Changzhou University, Changzhou 213164, Jiangsu, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2296. doi: 10.1107/S1600536812029182. Epub 2012 Jun 30.

DOI:10.1107/S1600536812029182
PMID:22798937
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3394072/
Abstract

In the title compound, C(24)H(28)N(2)O(4), the dioxalane ring has an envelope conformation. The cyclo-hexane ring adopts a chair conformation. The dihedral angle between the benzene rings is 72.5 (3)°. The mol-ecular conformation is stabilized by two intra-molecular O-H⋯N hydrogen-bonding inter-actions with an S(6) graph-set motif. The crystal structure is stabilized by van der Waals inter-actions.

摘要

在标题化合物C(24)H(28)N(2)O(4)中，二氧戊环具有信封式构象。环己烷环呈椅式构象。苯环之间的二面角为72.5 (3)°。分子构象通过两个具有S(6)图形集 motif的分子内O-H⋯N氢键相互作用得以稳定。晶体结构通过范德华相互作用得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b723/3394072/365b7c058b2a/e-68-o2296-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b723/3394072/365b7c058b2a/e-68-o2296-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b723/3394072/365b7c058b2a/e-68-o2296-fig1.jpg

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本文引用的文献

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