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六方十二棱柱十二聚水簇：五重穿插六连接超分子网络的构筑单元。

Hexagonal prismatic dodecameric water cluster: a building unit of the five-fold interpenetrating six-connected supramolecular network.

机构信息

Fujian Key Laboratory of Polymer Materials, College of Materials Science and Engineering, Fujian Normal University, Fuzhou, Fujian, 350007, P. R. China.

出版信息

Chem Commun (Camb). 2012 Sep 18;48(72):9014-6. doi: 10.1039/c2cc34412b. Epub 2012 Jul 17.

DOI:10.1039/c2cc34412b
PMID:22801735
Abstract

An experimental (H(2)O)(n) (n > 10) aggregate, similar to a theoretical hexagonal prismatic dodecameric water cluster structure, is characterized, the water cluster can be reversibly generated. The hydrogen bonds between the water clusters and bis(imidazolyl) ligand result in the formation of a five-fold interpenetrating six-connected supramolecular network.

摘要

一种实验性的（H2O）n（n>10）聚集体，类似于理论上的六方棱柱十二聚体水簇结构，其特征在于，该水簇可以可逆地生成。水簇与双（咪唑基）配体之间的氢键导致形成五重穿插的六连接超分子网络。

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