银炔化物团簇封装超分子盒的双重模板合成。
Dual templated synthesis of silver acetylide cluster-encapsulated supramolecular boxes.
机构信息
The Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China.
出版信息
Chem Commun (Camb). 2012 Aug 28;48(67):8368-70. doi: 10.1039/c2cc33757f. Epub 2012 Jul 16.
PMID:22801736
Abstract
A dual-templated approach for the controllable synthesis of metal cluster complexes is described. By using an acetylide-containing anion with specific geometry as a central template and a macrocyclic coordinative compound as a peripheral one, two multinuclear silver-acetylide cluster-encapsulated supramolecular boxes were synthesized.
摘要
本文描述了一种双模板可控合成金属簇合物的方法。通过使用具有特定几何形状的含乙炔阴离子作为中心模板和大环配位化合物作为外围模板，合成了两种多核银-乙炔化物簇封装的超分子盒。
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