[2-(1-{2-[Aza-nid-yl(ethyl-sulfan-yl)methyl-idene-κN]hydrazin-1-yl-idene-κN(1)}eth-yl)phenolato-κO](dimethyl sulfoxide-κO)dioxidomolybdenum(VI).
作者信息
Takjoo Reza, Ng Seik Weng, Tiekink Edward R T
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m944-5. doi: 10.1107/S1600536812026566. Epub 2012 Jun 20.
Abstract
The Mo(VI) atom in the title complex, [Mo(C(11)H(13)N(3)OS)O(2)(C(2)H(6)OS)], is N,N',O-coordinated by the dianionic tridentate ligand, two mutually cis oxide O atoms and a dimethyl sulfoxide O atom, defining a distorted octa-hedral N(2)O(4) donor set. The most prominent feature of the crystal packing is the formation of inversion dimers via pairs of N-H⋯O hydrogen bonds and eight-membered {⋯HNMoO}(2) loops. The Schiff base ligand is disordered over two orientations of equal occupancy.
摘要
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本文引用的文献
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[2-(1-{2-[Aza-nid-yl(ethyl-sulfan-yl)methyl-idene-κN]hydrazin-1-yl-idene-κN¹}eth-yl)phenolato-κO](pyridine-κN)nickel(II).[2-(1-{2-[氮杂环丁烷基(乙硫基)亚甲基-κN]肼-1-亚基-κN¹}乙基)苯酚根-κO](吡啶-κN)镍(II)
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