6,6'-二甲基-2,2'-联吡啶-1-鎓四氯合金(III)酸盐
6,6'-Dimethyl-2,2'-bipyridin-1-ium tetra-chloridoaurate(III).
作者信息
Zare Dehnavi Marzieh, Abedi Anita
机构信息
Department of Chemistry, North Tehran Branch, Islamic Azad University, Tehran, Iran.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m981. doi: 10.1107/S160053681202853X. Epub 2012 Jun 30.
Abstract
In the anion of the title compound, (C(12)H(13)N(2))[AuCl(4)], the Au(III) atom has a square-planar coordination. In the crystal, inter-molecular N-H⋯Cl and C-H⋯Cl hydrogen bonds and π-π contacts between the pyridine rings [centroid-centroid distance = 3.5419 (19) Å] result in the formation of a supra-molecular structure.
摘要
在标题化合物(C₁₂H₁₃N₂)[AuCl₄]的阴离子中，Au(III)原子具有平面正方形配位。在晶体中，分子间的N-H⋯Cl和C-H⋯Cl氢键以及吡啶环之间的π-π接触[质心-质心距离 = 3.5419 (19) Å]导致形成超分子结构。
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