（甲醇-κO）（甲醇根-κO）氧代[N-（2-氧化苄叉基）异亮氨酸根-κ（3）O，N，O']钒（V）
(Methanol-κO)(methano-lato-κO)oxido[N-(2-oxidobenzyl-idene)isoleucinato-κ(3)O,N,O']vanadium(V).
作者信息
Wang Chengyuan, Guo Zhenghua, Dong Jianfang, Li Lianzhi
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m982. doi: 10.1107/S1600536812028231. Epub 2012 Jun 30.
In the title complex, [V(C(13)H(15)NO(3))O(CH(3)O)(CH(3)OH)], the V(V) atom is six-coordinated by a tridentate O,N,O'-donor ligand, derived from the condensation of salicyl-aldehyde and l-isoleucine, a vanadyl O atom, a methano-late O atom and a methanol O atom in a distorted octa-hedral geometry. The asymmetric unit contains two complex mol-ecules. In the crystal, inter-molecular O-H⋯O and C-H⋯O hydrogen bonds connect the mol-ecules into a one-dimensional chain along [100].
在标题配合物[V(C₁₃H₁₅NO₃)O(CH₃O)(CH₃OH)]中，V(V)原子由一个三齿O,N,O'供体配体六配位，该配体衍生自水杨醛与L-异亮氨酸的缩合反应，一个氧钒O原子、一个甲醇盐O原子和一个甲醇O原子，呈扭曲的八面体几何构型。不对称单元包含两个配合物分子。在晶体中，分子间的O—H⋯O和C—H⋯O氢键将分子沿[100]方向连接成一维链。
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