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Benzene-1,2-dicarb-oxy-lic acid-pyridinium-2-olate (1/1).

作者信息

Yu Chua-Hua

机构信息

Orderd Matter Science Research Center, Southeast University, Nanjing 211189, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o1989. doi: 10.1107/S1600536812023914. Epub 2012 Jun 2.

Abstract

The asymmetric unit of the title compound, C(5)H(5)NO·C(8)H(6)O(4), contains one o-phthalate acid mol-ecule and one pyridin-2-ol mol-ecule, which exists in a zwitterionic form. In the o-phthalate acid mol-ecule, the carboxyl-ate groups are twisted from the benzene ring by dihedral angles of 13.6 (1)° and 73.1 (1)°; the hy-droxy H atom in the latter group is disordered over two positons in a 1:1 ratio. In the crystal, O-H⋯O and N-H⋯O hydrogen bonds link the mol-ecules into zigzag chains in [-101].

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd91/3393265/3bee910789c6/e-68-o1989-fig1.jpg

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