Zhao Min-Min
College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, P. R. China.
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2022. doi: 10.1107/S1600536812024993. Epub 2012 Jun 13.
In the title compound, C(6)H(7)ClN(+)·Br(-), the amino N atom is protonated. All non-H atoms of the cation are essentially coplanar [r.m.s. deviation = 0.004 (3) Å]. In the crystal, N-H⋯Br hydrogen bonds connect the ions, forming a ribbon-like structure propagating along [010].
在标题化合物C(6)H(7)ClN(+)·Br(-)中,氨基N原子被质子化。阳离子的所有非H原子基本共面[r.m.s.偏差 = 0.004 (3) Å]。在晶体中,N-H⋯Br氢键连接离子,形成沿[010]方向延伸的带状结构。