Zhang Min-juan, Zhang Ji-long, Wang Zhi-bin, Jing Ning, Hao Jian
Key Laboratory of Instrumentation Science & Dynamic Measurement (North University of China), Ministry of Education, Taiyuan 030051, China.
Guang Pu Xue Yu Guang Pu Fen Xi. 2012 May;32(5):1203-8.
In the Fourier transform infrared spectrometers the interferograms are usually sampled by the means of the single-side beyond zero path difference and the interferograms are asymmetric. These phase-corrected technologies are researched and improved in the present paper. In the Mertz method which requires apodization to be higher, the interferograms are apodized by these asymmetric windows so that the width of the main lobe increases and spectral resolution reduced. In order to solve these problems, a method which combines the Mertz and Forman methods is presented in the paper. In the method a double-side interferogram is constructed by the mirrored processing of the single-side interferogram beyond zero path difference, followed by the symmetric apodization, fast Fourier transform (FFT) to rebuild spectrum. And in the method high resolution phase spectrum is computed by the symmetrization of double-side interfergram to improve the phase-correction accuracy. In the experiment, these asymmetric window functions have the lower resolution compared with these symmetric window functions. And the spectrum which is acquired by the improved phase corrected method is compared with the spectra which are acquired by the Mertz and Forman methods, and the improved method has less error than Mertz, less computation than Forman, and the spectral resolution achieved 2 cm(-1).
在傅里叶变换红外光谱仪中,干涉图通常采用单边过零光程差采样,干涉图不对称。本文对这些相位校正技术进行了研究和改进。在需要更高变迹的默茨方法中,干涉图通过这些不对称窗口进行变迹,使得主瓣宽度增加且光谱分辨率降低。为了解决这些问题,本文提出了一种将默茨方法和福尔曼方法相结合的方法。该方法通过对单边过零光程差干涉图进行镜像处理构建双边干涉图,随后进行对称变迹、快速傅里叶变换(FFT)以重建光谱。并且该方法通过双边干涉图的对称化计算高分辨率相位谱,以提高相位校正精度。实验中,这些不对称窗函数与对称窗函数相比分辨率较低。将改进的相位校正方法获取的光谱与默茨方法和福尔曼方法获取的光谱进行比较,改进方法比默茨方法误差更小,比福尔曼方法计算量更小,且光谱分辨率达到了2 cm⁻¹ 。