Laboratoire de Spectrochimie Infrarouge et Raman UMR-CNRS 8516, Bât. C5 Université des Sciences et Technologies de Lille, 59655 Villeneuve d'Ascq cedex, France.
Photochem Photobiol Sci. 2012 Oct;11(10):1515-9. doi: 10.1039/c2pp25121c.
We report the activation energy determination corresponding to the recombination of the radical cation electron moiety created through photoionization of the 1,6-diphenyl-1,3,5-hexatriene molecule incorporated in ZSM-5 zeolite channels. We demonstrate that the charge separated state stabilization in zeolite does not depend only on the Al content but also on the Al repartition.
我们报告了相应的激活能的确定通过光离子化的 1,6-二苯基-1,3,5-己三烯分子在 ZSM-5 沸石通道中创建的自由基阳离子电子部分的复合。我们证明在沸石中的电荷分离状态的稳定化不仅取决于 Al 含量，而且还取决于 Al 的分配。
