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从玉米秸秆中制备纤维素及其在水溶液中吸附镉离子的应用。

Preparation of cellulose derived from corn stalk and its application for cadmium ion adsorption from aqueous solution.

机构信息

College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510006, PR China.

出版信息

Carbohydr Polym. 2012 Oct 1;90(2):1008-15. doi: 10.1016/j.carbpol.2012.06.035. Epub 2012 Jun 21.

Abstract

Cellulose was isolated from corn stalk and modified by graft copolymerization to produce an absorbent material (AGCS-cell), which was characterized by scanning electron microscope and energy disperse spectroscopy (SEM-EDS), X-ray diffraction (XRD) and solid-state CP/MAS (13)C NMR. The results showed that AGCS-cell had better adsorption potential for cadmium ion than unmodified cellulose because of the addition of functional groups (CN and OH groups) and the lower crystallinity. The Langmuir isotherms gave the best fit to the data and gave an adsorption capacity was 21.37 mg g(-1), which was close to unpurified cellulose (AGCS) and reflected the feasibility of using AGCS-cell as an adsorbent to remove cadmium ions.

摘要

从玉米秸秆中分离出纤维素,并通过接枝共聚进行改性,得到一种具有吸收能力的材料(AGCS-细胞)。通过扫描电子显微镜和能量色散光谱(SEM-EDS)、X 射线衍射(XRD)和固态 CP/MAS(13)C NMR 对其进行了表征。结果表明,AGCS-细胞对镉离子具有更好的吸附能力,因为其具有更多的功能基团(CN 和 OH 基团)和较低的结晶度。Langmuir 等温线对数据拟合得最好,吸附容量为 21.37mg/g,这与未提纯的纤维素(AGCS)相近,反映了使用 AGCS-细胞作为吸附剂去除镉离子的可行性。

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