二碘化钐-水体系化学的最新进展
Recent advances in the chemistry of SmI(2)-H(2)O.
作者信息
Sautier Brice, Procter David J
机构信息
University of Manchester, School of Chemistry, Oxford Road, Manchester M13 9PL, UK.
出版信息
Chimia (Aarau). 2012;66(6):399-403. doi: 10.2533/chimia.2012.399.
PMID:22871283
Abstract
Recent work from our laboratories has shown SmI(2)-H(2)O to be a versatile, readily-accessible and non-toxic reductant that is more powerful than SmI(2). This review describes the reduction of functional groups that were previously thought to lie beyond the reach of SmI(2) and complexity-generating cyclisations and cyclisation cascades triggered by the reduction of the ester carbonyl group with SmI(2)-H(2)O.
摘要
我们实验室最近的研究表明，SmI(2)-H(2)O是一种多功能、易于获取且无毒的还原剂，其还原能力比SmI(2)更强。本综述描述了以前认为超出SmI(2)还原范围的官能团的还原，以及由SmI(2)-H(2)O还原酯羰基引发的生成复杂性的环化反应和环化串联反应。
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