构象对双稳态给体-受体 [3] 轮烷中非共价键相互作用的影响。
The effects of conformation on the noncovalent bonding interactions in a bistable donor-acceptor [3]catenane.
机构信息
Center for the Chemistry of Integrated Systems, Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA.
出版信息
Chem Commun (Camb). 2012 Sep 25;48(74):9245-7. doi: 10.1039/c2cc34190e. Epub 2012 Aug 8.
PMID:22874839
Abstract
A switchable donor-acceptor bistable [3]catenane, composed of a crown ether containing a pair of alternating π-electron rich tetrathiafulvalene and 1,5-dioxynaphthalene units, encircled by two π-electron deficient cyclobis(paraquat-p-phenylene) rings, has been synthesised and the redox-activated switching it undergoes investigated.
摘要
一种可切换的给体-受体双稳态[3]索烃，由一个冠醚组成，其中包含一对交替的π-富四硫富瓦烯和 1,5-二氧萘单元，由两个π-缺电子环双（对亚甲基-对苯醌）环环绕，已经被合成，并研究了它经历的氧化还原激活开关。
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