苯亚甲基恶唑酮作为分子光开关。
Benzylidene-oxazolones as molecular photoswitches.
机构信息
Departamento de Química, Centro de Investigación en Síntesis Química (CISQ), Universidad de La Rioja, Madre de Dios, 51, E-26006, Logroño, La Rioja, Spain.
出版信息
Org Lett. 2012 Sep 7;14(17):4334-7. doi: 10.1021/ol301741g. Epub 2012 Aug 9.
PMID:22877084
Abstract
The synthesis and photochemical study of a family of molecular switches inspired by the green fluorescent protein (GFP) chromophore is presented. These compounds can be easily synthesized, and their photophysical properties may be tuned. Due to their efficient photoisomerization and high stability, these compounds can be switched on/off by using light and heat or light with different wavelengths.
摘要
本文介绍了受绿色荧光蛋白（GFP）发色团启发的一类分子开关的合成和光化学研究。这些化合物可以很容易地合成，其光物理性质也可以进行调节。由于它们具有高效的光致异构化和高稳定性，可以通过光和热或不同波长的光来开启/关闭这些化合物。
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