Physics Department, Shanghai Key Laboratory of Magnetic Resonance, East China Normal University, China.
Chemphyschem. 2012 Nov 12;13(16):3585-8. doi: 10.1002/cphc.201200548. Epub 2012 Aug 13.
I still see you: a new pulse sequence, SHA+, little sensitive to dipolar truncation, allows direct or relayed polarization transfer between (13)C atoms, distant by 3.5-9.6 Å, in amyloid fibrils. SHA+ can also be used in a broadband way with the weak rf-condition of ν(1)/ν(R)≈0.2-0.3 which permits the investigation of temperature-sensitive biological systems.
一种新的脉冲序列,SHA+,对偶极截断的敏感性很小,允许在淀粉样纤维中相隔 3.5-9.6Å 的 (13)C 原子之间进行直接或间接的极化转移。SHA+ 也可以在较弱的射频条件 ν(1)/ν(R)≈0.2-0.3 下以宽带方式使用,这允许研究对温度敏感的生物系统。