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一种氮掺杂聚苯胺碳,具有高电催化活性和稳定性,可用于燃料电池中的氧还原反应。

A nitrogen-doped polyaniline carbon with high electrocatalytic activity and stability for the oxygen reduction reaction in fuel cells.

机构信息

Division of Energy Storage, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, No.457 Zhongshan Road, Dalian 116023, PR China.

出版信息

ChemSusChem. 2012 Sep;5(9):1698-702. doi: 10.1002/cssc.201200178. Epub 2012 Aug 13.

DOI:10.1002/cssc.201200178
PMID:22890976
Abstract

PANI-BASED CARBON CAT: A low-cost nitrogen-doped carbon nanomaterial from polyaniline as fuel cell cathode electrocatalyst is prepared by chemical polymerization of aniline monomers, followed by pyrolysis in the presence of ammonia. The catalyst demonstrates high activity, with an onset potential comparable to, and a reduction current higher than, a commercial platinum catalyst.

摘要

基于 PANI 的碳 CAT:一种低成本的氮掺杂碳纳米材料,由苯胺单体的化学聚合制备,然后在氨存在下进行热解。该催化剂表现出高活性,其起始电位可与商业铂催化剂相媲美,还原电流高于商业铂催化剂。

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引用本文的文献

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The Facile Production of -Chloroaniline Facilitated by an Efficient and Chemoselective Metal-Free N/S Co-Doped Carbon Catalyst.高效、化学选择性的无金属 N/S 共掺杂碳催化剂促进 - 氯苯胺的简便制备。
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B and N isolate-doped graphitic carbon nanosheets from nitrogen-containing ion-exchanged resins for enhanced oxygen reduction.从含氮离子交换树脂中制备硼和氮共掺杂的石墨化碳纳米片用于增强氧还原反应
Sci Rep. 2014 Jun 5;4:5184. doi: 10.1038/srep05184.