Division of Advanced Materials, Korea Research Institute of Chemical Technology, P.O. Box 107, 141 Gajeong-Ro, Yuseong-Gu, Daejeon 305-600, Republic of Korea.
J Org Chem. 2012 Sep 21;77(18):8329-31. doi: 10.1021/jo300831u. Epub 2012 Aug 29.
We developed a new synthetic method for bicyclo[2.2.2]octadiene (BCOD)-fused porphyrin (1), a tetrabenzoporphyrin (TBP, 2) precursor that is well-known as a good material for use in organic electronic devices. The newly developed method synthesizes the BCOD-fused pyrrole intermediate (which is the most important intermediate in synthesizing BCOD-fused porphyrin) in a simpler and easier manner than other existing methods, and thus, the new method can efficiently synthesize the TBP precursor.
我们开发了一种新的合成方法，用于合成双环[2.2.2]辛二烯（BCOD）-稠合卟啉（1），这是一种四苯并卟啉（TBP）的前体，是用于有机电子器件的良好材料。新开发的方法比其他现有方法更简单、更容易地合成 BCOD-稠合吡咯中间体（这是合成 BCOD-稠合卟啉的最重要中间体），因此，新方法可以有效地合成 TBP 前体。
