Mafud Ana C, Gambardella Maria Teresa Prado
Instituto de Física de São Carlos, Universidade de São Paulo, Av. Trabalhador Sãocarlense, 400, Caixa Postal 369, 13566-590 São Carlos, SP, Brazil.
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):m1025. doi: 10.1107/S1600536812029613. Epub 2012 Jul 4.
In the ionic title compound, K(+)·C(5)H(8)NOS(2) (-)·H(2)O, the morpholine ring of the morpholine-4-carbodithio-ate anion has a chair conformation. The potassium cation is coordinated by four S and four O atoms in a bipyramidal reversed geometry. In the crystal, the three components are linked, generating infinite two-dimensional networks that lie parallel to the bc plane. These layers are linked via O-H⋯S hydrogen bonds, forming a three-dimensional structure.
在离子型标题化合物K⁺·C₅H₈NOS₂⁻·H₂O中，吗啉-4-碳二硫代酸根阴离子的吗啉环呈椅式构象。钾阳离子以双锥反转几何构型由四个硫原子和四个氧原子配位。在晶体中，这三种组分相互连接，形成平行于bc平面的无限二维网络。这些层通过O—H⋯S氢键相连，形成三维结构。
