Saphu Watcharin, Chanthee Songwuit, Chainok Kittipong, Harding David J, Pakawatchai Chaveng
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):m1026. doi: 10.1107/S1600536812029364. Epub 2012 Jul 4.
In the title compound, [Mn(NO(3))(2)(C(12)H(8)N(2))(2)], the Mn(II) atom lies on a twofold rotation axis, and is six-coordinated in a distorted trans-N(4)O(2) octa-hedral environment by four N atoms from two 1,10-phenanthroline ligands and two O atoms from two nitrate anions. The nitrate anion is disordered about a twofold rotation axis with fixed occupancy factors of 0.5. In the crystal, mol-ecules are linked by weak C-H⋯O hydrogen bonds and π-π stacking inter-actions [centroid-centroid distance = 4.088 (5) Å] into a three-dimensional supra-molecular network.
在标题化合物[Mn(NO₃)₂(C₁₂H₈N₂)₂]中,锰(II)原子位于一个二重旋转轴上,在一个扭曲的反式-N₄O₂八面体环境中通过来自两个1,10-菲咯啉配体的四个氮原子和来自两个硝酸根阴离子的两个氧原子进行六配位。硝酸根阴离子围绕一个二重旋转轴无序排列,占据因子固定为0.5。在晶体中,分子通过弱的C-H⋯O氢键和π-π堆积相互作用[质心-质心距离 = 4.088 (5) Å]连接成一个三维超分子网络。