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Bis[2,6-bis-(1-methyl-1H-benzimidazol-2-yl-κN(3))pyridine-κN]zinc dipicrate methanol disolvate.

作者信息

Fan Xuyang, Yuan Jingkun, Bai Ying, Kong Jin, Wu Huilu

机构信息

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):m1072. doi: 10.1107/S1600536812031443. Epub 2012 Jul 14.

DOI:10.1107/S1600536812031443
PMID:22904739
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3414132/
Abstract

In the title compound, Zn(C(21)H(17)N(5))(2)(2)·2CH(3)OH, the Zn(II) atom is coordinated by six N atoms from two tridentate 2,6-bis-(1-methyl-1H-benzimidazol-2-yl)pyridine ligands in a distorted octa-hedral environment. In the crystal, the picrate anions and methanol solvent mol-ecules are connected by O-H⋯O hydrogen bonds. Weak inter-molecular C-H⋯O hydrogen bonds are also observed.

摘要

相似文献

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本文引用的文献

1
The chemistry of the benzimidazoles.苯并咪唑的化学性质。
Chem Rev. 1951 Jun;48(3):397-541.
2
Bis[2,6-bis-(1H-benzimidazol-2-yl)pyridine]-nickel(II) dipicrate dimethyl-formamide disolvate.
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 17;66(Pt 8):m967. doi: 10.1107/S160053681002773X.
3
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
4
The combinatorial synthesis of bicyclic privileged structures or privileged substructures.双环优势结构或优势子结构的组合合成。
Chem Rev. 2003 Mar;103(3):893-930. doi: 10.1021/cr020033s.
5
Metal Activation of Enzymes in Nucleic Acid Biochemistry.核酸生物化学中酶的金属激活作用
Chem Rev. 1998 May 7;98(3):1067-1088. doi: 10.1021/cr960436q.