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二-μ-乙酸根-κ(4)O:O-双-({N'-[(E)-苯基-(吡啶-2-基-κN)亚甲基]苯甲酰肼基-κ(2)N',O}铜(II))

Di-μ-acetato-κ(4)O:O-bis-({N'-[(E)-phen-yl-(pyridin-2-yl-κN)methyl-idene]benzo-hydrazidato-κ(2)N',O}copper(II)).

作者信息

Vineetha M C, Sithambaresan M, Jacob Jinsa Mary, Kurup M R Prathapachandra

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):m1086-7. doi: 10.1107/S1600536812031467. Epub 2012 Jul 18.

DOI:10.1107/S1600536812031467
PMID:22904748
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3414141/
Abstract

The binuclear molecule of the title compound, [Cu(2)(C(19)H(14)N(3)O)(2)(CH(3)COO)(2)], resides on a crystallographic inversion centre. It has an E conformation with respect to the azomethine double bond and a Z conformation about the amide C=N bond. The Cu(II) atom has a slightly distorted square-pyramidal coordination geometry. The crystal packing involves inter-molecular C-H⋯O, C-H⋯N and C-H⋯π and two types of π-π inter-actions, with centroid-centroid distances of 3.9958 (10) and 3.7016 (13) Å.

摘要

标题化合物[Cu₂(C₁₉H₁₄N₃O)₂(CH₃COO)₂]的双核分子位于一个晶体学倒转中心上。就偶氮甲碱双键而言，它具有E构型，而就酰胺C=N键而言，它具有Z构型。Cu(II)原子具有略微扭曲的四方锥配位几何结构。晶体堆积涉及分子间的C-H⋯O、C-H⋯N和C-H⋯π相互作用以及两种类型的π-π相互作用，质心间距分别为3.9958 (10)和3.7016 (13) Å。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb62/3414141/99433529865a/e-68-m1086-fig6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb62/3414141/49d24a156683/e-68-m1086-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb62/3414141/83b182ed30df/e-68-m1086-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb62/3414141/6c2f2c48d08c/e-68-m1086-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb62/3414141/d4c97c059726/e-68-m1086-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb62/3414141/a84aa67eaf10/e-68-m1086-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb62/3414141/99433529865a/e-68-m1086-fig6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb62/3414141/49d24a156683/e-68-m1086-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb62/3414141/83b182ed30df/e-68-m1086-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb62/3414141/6c2f2c48d08c/e-68-m1086-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb62/3414141/d4c97c059726/e-68-m1086-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb62/3414141/a84aa67eaf10/e-68-m1086-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb62/3414141/99433529865a/e-68-m1086-fig6.jpg

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