Fun Hoong-Kun, Chia Tze Shyang, Al-Rashood Khalid A, Abdel-Aziz Hatem A
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):o2369. doi: 10.1107/S1600536812030346. Epub 2012 Jul 7.
The mol-ecule of the title compound, C(15)H(15)NO(3)S, has a twisted U-shaped conformation: the twist occurs at the central C-S(=O)(2)-C-C-C unit and the benzene ring makes a dihedral angle of 28.74 (7)° with the phenyl ring. The S-C-C=N torsion angle is -88.95 (13)°. In the crystal, inversion dimers linked by pairs of O-H⋯N hydrogen bonds generate R(2) (2)(6) loops, and C-H⋯O hydrogen bonds connect the dimers into a three-dimensional network.
标题化合物C(15)H(15)NO(3)S的分子具有扭曲的U形构象:扭曲发生在中心C-S(=O)(2)-C-C-C单元处,苯环与苯环的二面角为28.74 (7)°。S-C-C=N扭转角为-88.95 (13)°。在晶体中,由O-H⋯N氢键对连接的反演二聚体形成R(2) (2)(6)环,C-H⋯O氢键将二聚体连接成三维网络。