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4-氰基-1-甲基吡啶溴化物

4-Cyano-1-methyl-pyridinium bromide.

作者信息

Kammer Michael N, Mague Joel T, Koplitz Lynn V

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):o2409. doi: 10.1107/S1600536812030449. Epub 2012 Jul 10.

DOI:10.1107/S1600536812030449
PMID:22904863
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3414330/
Abstract

In the crystal of the title mol-ecular salt, C(7)H(7)N(2) (+)·Br(-), the cations form inversion dimers via weak pairwise C-H⋯N hydrogen bonds; their mean planes are separated by 0.292 (6) Å. Weak C-H⋯Br inter-actions involving all of the remaining H atoms tie the cations and anions together into sets of inter-penetrating sheets. The title compound is isostructural with its iodide analogue.

摘要

在标题分子盐C(7)H(7)N(2) (+)·Br(-)的晶体中,阳离子通过弱的成对C-H⋯N氢键形成反演二聚体;它们的平均平面相距0.292 (6) Å。涉及所有其余H原子的弱C-H⋯Br相互作用将阳离子和阴离子连接在一起形成相互贯穿的片层集合。标题化合物与其碘化物类似物同构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a1f7/3414330/737d6fa11684/e-68-o2409-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a1f7/3414330/39068753591c/e-68-o2409-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a1f7/3414330/737d6fa11684/e-68-o2409-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a1f7/3414330/39068753591c/e-68-o2409-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a1f7/3414330/737d6fa11684/e-68-o2409-fig2.jpg

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本文引用的文献

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