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1,1,1-三氯-2,2-双（4-碘苯基）乙烷

1,1,1-Trichloro-2,2-bis-(4-iodo-phen-yl)ethane.

作者信息

Smith Graham

机构信息

Science and Engineering Faculty, Queensland University of Technology, GPO Box 2434, Brisbane, Queensland 4001, Australia.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):o2504. doi: 10.1107/S1600536812032254. Epub 2012 Jul 21.

DOI:10.1107/S1600536812032254
PMID:22904944
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3414957/
Abstract

In the structure of the title compound, C(14)H(9)Cl(3)I(2), which is the 4-iodo-phenyl analogue of the insecticide DDT [1,1,1-tri-chloro-2,2-bis-(4-chloro-phen-yl)ethane], isomorphism between the two compounds has been confirmed. In the mol-ecule, the dihedral angle between the planes of the two benzene rings is 65.8 (4)° which compares with 64.7 (7)° in DDT.

摘要

在标题化合物C(14)H(9)Cl(3)I(2)的结构中，它是杀虫剂滴滴涕[1,1,1-三氯-2,2-双-(4-氯苯基)乙烷]的4-碘苯基类似物，已证实这两种化合物之间存在同构现象。在分子中，两个苯环平面之间的二面角为65.8 (4)°，而滴滴涕中的该角度为64.7 (7)°。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d067/3414957/478a4eb65e24/e-68-o2504-fig1.jpg

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本文引用的文献

1
X-ray study of some DDT analogs.某些滴滴涕类似物的X射线研究。
J Am Chem Soc. 1946 Dec;68(12):2669. doi: 10.1021/ja01216a076.
2
Structure validation in chemical crystallography.化学晶体学中的结构验证
Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55. doi: 10.1107/S090744490804362X. Epub 2009 Jan 20.
3
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.

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