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（Z）-3-苄基-2-[(2-苯基-环己-2-烯基)亚氨基]-1,3-噻唑烷-4-酮

(Z)-3-Benzyl-2-[(2-phenyl-cyclo-hex-2-en-yl)imino]-1,3-thia-zolidin-4-one.

作者信息

Ooi Chin Wei, Fun Hoong-Kun, Quah Ching Kheng, Sathishkumar Murugan, Ponnuswamy Alagusundaram

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):o2563-4. doi: 10.1107/S1600536812033211. Epub 2012 Jul 28.

DOI:10.1107/S1600536812033211
PMID:22904992
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3415005/
Abstract

The title compound, C(22)H(22)N(2)OS, exists in a Z configuration with respect to the N=C bond. The cyclo-hexene ring adopts a distorted sofa conformation. The thia-zolidine ring is essentially planar, with a maximum deviation of 0.030 (2) Å, and forms dihedral angles of 76.66 (6) and 74.55 (6)° with the terminal phenyl rings. The dihedral angle between the phenyl rings is 71.55 (7)°. In the crystal, a C-H⋯π inter-action is observed.

摘要

标题化合物C(22)H(22)N(2)OS中，N=C键呈Z构型。环己烯环呈扭曲的沙发式构象。噻唑烷环基本为平面结构，最大偏差为0.030 (2) Å，与末端苯环形成的二面角分别为76.66 (6)°和74.55 (6)°。苯环之间的二面角为71.55 (7)°。在晶体中，观察到C-H⋯π相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0eae/3415005/d69462e84de6/e-68-o2563-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0eae/3415005/de859473b27e/e-68-o2563-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0eae/3415005/d69462e84de6/e-68-o2563-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0eae/3415005/de859473b27e/e-68-o2563-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0eae/3415005/d69462e84de6/e-68-o2563-fig2.jpg

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