（Z）-2- [（E）-2-（1-苯并噻吩-3-基-亚甲基）肼-1-基亚甲基] -1,2-二苯基乙酮
(Z)-2-[(E)-2-(1-Benzothio-phen-3-yl-methyl-idene)hydrazin-1-yl-idene]-1,2-diphenyl-ethanone.
作者信息
Pekdemir Merve, Işık Samil, Gümüş Sümeyye, Ağar Erbil, Soylu Mustafa Serkan
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):o2579-80. doi: 10.1107/S1600536812030978. Epub 2012 Jul 28.
The title compound, C(23)H(16)N(2)OS, is not planar, the phenyl ring of the benzoyl group making a dihedral of 77.61 (7)° with the benzothio-phene system ring. The benzothio-phene system and the remaining phenyl ring make an angle of 12.71 (13)°. The conformation around the imine functions is E for the C=N bond towards the benzothio-phene system and Z for the C=N bond towards the benzoyl group. The packing of the mol-ecules shows C-H⋯π inter-actions. A weak intramolecular C-H⋯N bond also occurs.
标题化合物C(23)H(16)N(2)OS不是平面结构，苯甲酰基的苯环与苯并噻吩体系环形成77.61 (7)°的二面角。苯并噻吩体系与其余苯环形成12.71 (13)°的夹角。对于朝向苯并噻吩体系的C=N键，亚胺官能团周围的构象为E型，而对于朝向苯甲酰基的C=N键，构象为Z型。分子堆积显示存在C-H⋯π相互作用。还存在一个弱的分子内C-H⋯N键。
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