Iturriza N, Nazmunnahar M, Dominguez L, González J, del Val J J
Department of Materials Physics, Faculty of Chemistry, UPV/EHU, Po Manuel de Lardizabal 3, 20018 San Sebastián, Spain.
J Nanosci Nanotechnol. 2012 Jun;12(6):5071-5. doi: 10.1166/jnn.2012.4885.
Experimental data on microstructural (crystalline volume fraction, grain size) and magnetic (coercive field) properties in amorphous and nanocrystalline Fe73.5-x(Co0.5Ni0.5)xSi13.5B9Nb3Cu1 alloy ribbons (x = 2.5, 5 and 10) are presented. Nanocrystalline structure was developed by annealing the precursor amorphous ribbons by current annealing (CA) and stress-current-annealing (SA). Microstructural analysis of the treated ribbons using X-ray Diffraction showed a high content of amorphous phase in the bulk. In addition, substantial changes in the crystalline state such as grain size of the samples annealed at different conditions were observed. The alloy composition also affects greatly the grain size,: increasing the (Co,Ni) content leads to higher values of the average grain size. The evolutions of the coercive field with the two kinds of thermal treatment were analysed, allowing us to conclude that the addition of (Co,Ni) tends to reduce the magnetic softness character of the original material, while the treated SA samples show higher coercivities higher than those treated without by CA.
本文给出了非晶态和纳米晶态Fe73.5-x(Co0.5Ni0.5)xSi13.5B9Nb3Cu1合金薄带(x = 2.5、5和10)的微观结构(晶相体积分数、晶粒尺寸)和磁性(矫顽场)性能的实验数据。通过电流退火(CA)和应力-电流退火(SA)对前驱体非晶薄带进行退火处理,从而形成纳米晶结构。利用X射线衍射对处理后的薄带进行微观结构分析,结果表明块状材料中存在高含量的非晶相。此外,还观察到在不同条件下退火的样品的晶态发生了显著变化,如晶粒尺寸。合金成分对晶粒尺寸也有很大影响:增加(Co,Ni)含量会导致平均晶粒尺寸增大。分析了两种热处理方式下矫顽场的演变情况,由此我们得出结论,添加(Co,Ni)倾向于降低原始材料的磁软特性,而经过SA处理的样品显示出比未经CA处理的样品更高的矫顽力。