Kobayashi A, Ando Y, Kurokawa K
JWRI, Osaka University, Ibaraki, Osaka 567-0047, Japan.
J Nanosci Nanotechnol. 2012 Jun;12(6):5106-10. doi: 10.1166/jnn.2012.4945.
Zirconia sprayed coatings are widely used as thermal barrier coatings (TBC) for high temperature protection of metallic structures. However, their use in diesel engine combustion chamber components has the long run durability problems, such as the spallation at the interface between the coating and substrate due to the interface oxidation. Although zirconia coatings have been used in many applications, the interface spallation problem is still waiting to be solved under the critical conditions such as high temperature and high corrosion environment. The gas tunnel type plasma spraying developed by the author can make high quality ceramic coatings such as Al2O3 and ZrO2 coating compared to other plasma spraying method. A high hardness ceramic coating such as Al2O3 coating by the gas tunnel type plasma spraying, were investigated in the previous study. The Vickers hardness of the zirconia (ZrO2) coating increased with decreasing spraying distance, and a higher Vickers hardness of about Hv = 1200 could be obtained at a shorter spraying distance of L = 30 mm. ZrO2 coating formed has a high hardness layer at the surface side, which shows the graded functionality of hardness. In this study, ZrO2 composite coatings (TBCs) with Al2O3 were deposited on SS304 substrates by gas tunnel type plasma spraying. The performance such as the mechanical properties, thermal behavior and high temperature oxidation resistance of the functionally graded TBCs was investigated and discussed. The resultant coating samples with different spraying powders and thickness are compared in their corrosion resistance with coating thickness as variables. Corrosion potential was measured and analyzed corresponding to the microstructure of the coatings.
High Heat Resistant Coatings, Gas Tunnel Type Plasma Spraying, Hardness,
氧化锆喷涂涂层作为金属结构高温防护的热障涂层(TBC)被广泛应用。然而,将其用于柴油发动机燃烧室部件存在长期耐久性问题,比如由于界面氧化导致涂层与基体之间的界面剥落。尽管氧化锆涂层已在许多应用中使用,但在高温和高腐蚀环境等关键条件下,界面剥落问题仍有待解决。作者研发的气隧道式等离子喷涂与其他等离子喷涂方法相比,能够制备高质量的陶瓷涂层,如Al2O3和ZrO2涂层。在之前的研究中,对气隧道式等离子喷涂制备的Al2O3等高硬度陶瓷涂层进行了研究。氧化锆(ZrO2)涂层的维氏硬度随喷涂距离减小而增加,在L = 30 mm的较短喷涂距离下可获得约Hv = 1200的较高维氏硬度。所形成的ZrO2涂层在表面一侧有一个高硬度层,显示出硬度的梯度功能。在本研究中,通过气隧道式等离子喷涂在SS304基体上沉积了含Al2O3的ZrO2复合涂层(TBC)。对功能梯度TBC的力学性能、热行为和高温抗氧化性能等进行了研究和讨论。将不同喷涂粉末和厚度的所得涂层样品以涂层厚度为变量比较其耐腐蚀性。测量并分析了与涂层微观结构相对应的腐蚀电位。
高耐热涂层;气隧道式等离子喷涂;硬度