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硼氢化镁：从储氢到镁电池。

Magnesium borohydride: from hydrogen storage to magnesium battery.

机构信息

Materials Research Department, Toyota Research Institute of North America, Ann Arbor, MI 48105, USA.

出版信息

Angew Chem Int Ed Engl. 2012 Sep 24;51(39):9780-3. doi: 10.1002/anie.201204913. Epub 2012 Aug 21.

DOI:10.1002/anie.201204913
PMID:22907926
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3588139/
Abstract

Beyond hydrogen storage: The first example of reversible magnesium deposition/stripping onto/from an inorganic salt was seen for a magnesium borohydride electrolyte. High coulombic efficiency of up to 94 % was achieved in dimethoxyethane solvent. This Mg(BH(4))(2) electrolyte was utilized in a rechargeable magnesium battery.

摘要

超越储氢

首例可逆镁沉积/剥离无机盐的例子出现在镁硼氢化盐电解质中。在二乙醚溶剂中，实现了高达 94%的高库仑效率。该 Mg(BH(4))(2)电解质被应用于可充电镁电池中。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3d20/3588139/40159325d534/anie0051-9780-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3d20/3588139/a40a1520638f/anie0051-9780-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3d20/3588139/d495686f5db9/anie0051-9780-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3d20/3588139/def0c0fd7ec0/anie0051-9780-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3d20/3588139/40159325d534/anie0051-9780-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3d20/3588139/a40a1520638f/anie0051-9780-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3d20/3588139/d495686f5db9/anie0051-9780-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3d20/3588139/def0c0fd7ec0/anie0051-9780-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3d20/3588139/40159325d534/anie0051-9780-f4.jpg

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1
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Appl Spectrosc. 2012 May;66(5):591-4. doi: 10.1366/11-06448.
2
Structure and compatibility of a magnesium electrolyte with a sulphur cathode.镁电解质与硫阴极的结构和相容性。
Nat Commun. 2011 Aug 9;2:427. doi: 10.1038/ncomms1435.
3
Building better batteries.制造更好的电池。
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Adv Sci (Weinh). 2023 Nov;10(32):e2304235. doi: 10.1002/advs.202304235. Epub 2023 Sep 24.
4
Calcium Metal Batteries with Long Cycle Life Using a Hydride-Based Electrolyte and Copper Sulfide Electrode.使用基于氢化物的电解质和硫化铜电极的长循环寿命钙金属电池。
Adv Sci (Weinh). 2023 Aug;10(22):e2301178. doi: 10.1002/advs.202301178. Epub 2023 May 19.
5
Insight into anomalous hydrogen adsorption on rare earth metal decorated on 2-dimensional hexagonal boron nitride: a density functional theory study.二维六方氮化硼负载稀土金属上反常氢吸附的洞察：密度泛函理论研究
RSC Adv. 2020 Mar 31;10(22):12929-12940. doi: 10.1039/d0ra01835j. eCollection 2020 Mar 30.
6
Complex Metal Borohydrides: From Laboratory Oddities to Prime Candidates in Energy Storage Applications.复杂金属硼氢化物：从实验室奇物到储能应用的主要候选物
Materials (Basel). 2022 Mar 19;15(6):2286. doi: 10.3390/ma15062286.
7
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JACS Au. 2022 Feb 11;2(2):463-471. doi: 10.1021/jacsau.1c00505. eCollection 2022 Feb 28.
8
Toggling Calcium Plating Activity and Reversibility through Modulation of Ca Speciation in Borohydride-based Electrolytes.通过调节硼氢化物基电解质中的钙形态来切换钙镀覆活性和可逆性。
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9
Enabling Mg metal anodes rechargeable in conventional electrolytes by fast ionic transport interphase.通过快速离子传输界面使镁金属阳极在传统电解质中可充电。
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Modeling of Electron-Transfer Kinetics in Magnesium Electrolytes: Influence of the Solvent on the Battery Performance.镁电解质中电子转移动力学的建模：溶剂对电池性能的影响。
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4
Prototype systems for rechargeable magnesium batteries.可充电镁电池的原型系统。
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