Davenport Research Laboratories, Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5H 3H5, Canada.
Org Biomol Chem. 2012 Oct 21;10(39):7900-2. doi: 10.1039/c2ob26503f.
Herein we report the development of an α-allylation reaction of α-boryl aldehydes that preserves the carbon-boron bond under Pd(0)/Pd(II) catalysis. A variety of α-boryl aldehydes and allylic alcohols participate in this chemoselective transformation. The α-allylated products were obtained as single regioisomers.
在此，我们报告了一种在 Pd(0)/Pd(II)催化下保留碳-硼键的α-烯丙基化反应的发展。各种α-硼基醛和烯丙醇参与了这种化学选择性转化。α-烯丙基化产物以单一区域异构体获得。
