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光致变色材料:远不止所见。

Photochromic materials: more than meets the eye.

机构信息

Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology, Shanghai 200237, P. R. China.

出版信息

Adv Mater. 2013 Jan 18;25(3):378-99. doi: 10.1002/adma.201201521. Epub 2012 Aug 22.

Abstract

Photochromic materials are a family of compounds which can undergo reversible photo-switches between two different states or isomers with remarkably different properties. Inspired by their smart photo-switchable characteristics, a variety of light-driven functional materials have been exploited, such as ultrahigh-density optical data storage, molecular switches, logic gates, molecular wires, optic/electronic devices, sensors, bio-imaging and so on. This review commences with a brief description of exciting progress in this field, from systems in solution to modified functional surfaces. Further development of these photo-switchable systems into practical applications as well as existing challenges are also discussed and put in prospect.

摘要

光致变色材料是一类化合物,它们可以在两种不同状态或异构体之间进行可逆的光开关转换,这些异构体具有显著不同的性质。受其智能光开关特性的启发,已经开发出了各种光驱动功能材料,例如超高密度光数据存储、分子开关、逻辑门、分子导线、光学/电子器件、传感器、生物成像等。本综述首先简要描述了该领域的令人兴奋的进展,从溶液中的体系到改性的功能表面。还讨论了这些光致变色体系进一步发展为实际应用以及当前面临的挑战,并对其进行了展望。

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