采用新型配体设计具有平面四配位碳的 Ag(I) 和 Au(I) 配合物。
Toward design of Ag(I) and Au(I) complexes with planar tetracoordinate carbon using novel ligands.
机构信息
Key Laboratory of Macromolecular Science of Shaanxi Province, School of Chemistry & Chemical Engineering, Shaanxi Normal University , Xi'an 710062, China.
出版信息
J Phys Chem A. 2012 Sep 13;116(36):9123-30. doi: 10.1021/jp305871m. Epub 2012 Aug 29.
PMID:22913722
Abstract
We have designed a family of novel molecules that can act as a donor at a carbon atom to coordinate with Ag(I) and Au(I) to achieve stable complexes with a planar tetracoordinate carbon (ptC). Then, a kind of new strategy for the design of the compound with a ptC was provided.
摘要
我们设计了一系列新型分子，它们可以作为碳原子上的供体与 Ag(I) 和 Au(I) 配位，形成具有平面四配位碳原子（ptC）的稳定配合物。然后，为设计具有 ptC 的化合物提供了一种新策略。
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