School of Materials Science and Engineering, Gwangju Institute of Science and Technology, Oryong-dong, Buk-gu, Gwangju 500-712, Republic of Korea.
ACS Nano. 2012 Sep 25;6(9):8166-72. doi: 10.1021/nn3028776. Epub 2012 Aug 28.
We demonstrate a high-performance selection device by utilizing the concept of crested oxide barrier to suppress the sneak current in bipolar resistive memory arrays. Using a TaO(x)/TiO(2)/TaO(x) structure, high current density over 10(7) A cm(-2) and excellent nonlinear characteristics up to 10(4) were successfully demonstrated. On the basis of the defect chemistry and SIMS depth profile result, we found that some Ta atoms gradually diffused into TiO(2) film, and consequently, the energy band of the TiO(2) film was symmetrically bent at the top and bottom TaO(x)/TiO(2) interfaces and modified as a crested oxide barrier. Furthermore, the one selector-one resistor device exhibited significant suppression of the leakage current, indicating excellent selector characteristics.
我们展示了一种高性能选择器件,利用尖晶石氧化物势垒的概念来抑制双极电阻存储阵列中的 sneak 电流。使用 TaO(x)/TiO(2)/TaO(x) 结构,成功地展示了超过 10(7) A cm(-2)的高电流密度和高达 10(4)的优异非线性特性。基于缺陷化学和 SIMS 深度剖析结果,我们发现一些 Ta 原子逐渐扩散到 TiO(2) 薄膜中,从而使 TiO(2) 薄膜的能带在顶部和底部 TaO(x)/TiO(2) 界面处对称弯曲,并改造成尖晶石氧化物势垒。此外,一个选择器一个电阻器的器件表现出对泄漏电流的显著抑制,表明了优异的选择器特性。