Department of Polymer Chemistry, Chemnitz University of Technology, Strasse der Nationen 62, 09107 Chemnitz, Germany.
Chem Commun (Camb). 2012 Oct 11;48(79):9867-9. doi: 10.1039/c2cc34775j. Epub 2012 Aug 28.
Defect-free microporous carbon layers on graphite can be produced by DABCO-catalyzed twin polymerization of 2,2'-spirobi[4H-1,3,2-benzodioxasiline] in a slurry polymerization and subsequent thermal transformation of the resulting phenolic resin into carbon.
在双(二甲氨基)二环[2.2.2]辛烷(DABCO)催化下,将 2,2'-螺[4H-1,3,2-苯并二氧杂硅环]浆状聚合,然后将所得酚醛树脂热转化为碳,可以在石墨上生成无缺陷的微孔碳层。