Department of Chemistry, University of Glasgow, United Kingdom.
Chirality. 2012 Dec;24(12):957-8. doi: 10.1002/chir.22106. Epub 2012 Aug 28.
The discrete symmetries of parity P, time reversal T, and charge conjugation C may be used to characterize the properties of chiral systems. It is well known that parity violation infiltrates into ordinary matter via an interaction between the nucleons and electrons, mediated by the Z(0) particle, that lifts the degeneracy of the mirror-image enantiomers of a chiral molecule. Being odd under P but even under T, this P-violating interaction exhibits true chirality and so may induce absolute enantioselection under all circumstances. It has been suggested that CP violation may also infiltrate into ordinary matter via a P-odd, T-odd interaction mediated by the (as yet undetected) axion. This CP-violating interaction exhibits false chirality and so may induce absolute enantioselection in processes far from equilibrium. Both true and false cosmic chirality should be considered together as possible sources of homochirality in the molecules of life.
宇称 P、时间反演 T 和电荷共轭 C 的离散对称性可用于描述手征系统的性质。众所周知,通过核子与电子之间的相互作用,通过 Z(0) 粒子介导,宇称破坏会渗透到普通物质中,从而消除手征分子镜像对映异构体的简并性。这种违反宇称的相互作用在 P 下是奇数但在 T 下是偶数,表现出真正的手征性,因此在任何情况下都可能导致绝对对映选择性。有人认为,CP 破坏也可能通过 P 奇数、T 奇数相互作用,通过(尚未检测到的)轴子介导,渗透到普通物质中。这种 CP 破坏相互作用表现出虚假的手征性,因此可能在手征性远非平衡的过程中诱导绝对对映选择性。真正的和虚假的宇宙手征性都应该被视为生命分子中同手性的可能来源。