Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstrasse 40, 48149 Münster, Germany.
J Am Chem Soc. 2012 Sep 19;134(37):15241-4. doi: 10.1021/ja306622y. Epub 2012 Sep 5.
An efficient and highly asymmetric ruthenium-N-heterocyclic carbene-catalyzed hydrogenation of substituted thiophenes and benzothiophenes is described, providing a new strategy for the formation of valuable enantiomerically pure tetrahydrothiophenes and 2,3-dihydrobenzothiophenes.
描述了一种高效且高度不对称的钌-N-杂环卡宾催化取代噻吩和苯并噻吩的氢化反应，为形成有价值的对映纯四氢噻吩和 2,3-二氢苯并噻吩提供了新策略。
